Lunar MaficOne of the two broad categories of silicate minerals, the other being felsic, based on its magnesium (Mg) and/or iron (Fe) content. Mafic indicates silicate minerals that are predominantly comprised of Mg and/or Fe.The term is derived from those major constituents: Magnesium + Ferrum (Latin for iron) + ic (having Click on Term to Read More, Th-rich, Impact-Melt BrecciaWork in Progress ... A rock that is a mechanical mixture of different minerals and/or rock fragments (clasts). A breccia may also be distinguished by the origin of its clasts: (monomict breccia: monogenetic or monolithologic, and polymict breccia: polygenetic or polylithologic). The proportions of these fragments within the unbrecciated material Click on Term to Read More (KREEP-melt regolithMixture of unconsolidated rocky fragments, soil, dust and other fine granular particles blanketing the surface of a body lacking an atmosphere. Regolith is the product of "gardening" by repeated meteorite impacts, and thermal processes (such as repeated heating and cooling cycles). Click on Term to Read More breccia) Found Summer of 2006 no coordinates recorded Two paired stones weighing 64.3 g (NWA 4472) and 188 g (NWA 4485) were found in the Algerian desert and subsequently purchased by separate collectors (G. Hupé and S. Ralew, respectively). A portion of each was submitted for analysis to the University of Washington in Seattle (S. Kuehner and A. Irving) and Washington University in St. Louis (R. Korotev), and the meteoriteWork in progress. A solid natural object reaching a planet’s surface from interplanetary space. Solid portion of a meteoroid that survives its fall to Earth, or some other body. Meteorites are classified as stony meteorites, iron meteorites, and stony-iron meteorites. These groups are further divided according to their mineralogy and Click on Term to Read More was classified as a unique KREEP-rich, basaltic melt breccia.
This is a polymict brecciaGeneral term for all breccias that are neither monomict nor dimict. Modified from image source: http://www.saharamet.com/meteorite/gallery/HED/index.html. composed of clasts from diverse lunar locations including mareBroad low plains surrounded by basin-forming mountains, originally thought to be a sea (pl. maria). This term is applied to the basalt-filled impact basins common on the face of the Moon visible from Earth. Click on Term to Read MorebasaltBasalt is the most common extrusive igneous rock on the terrestrial planets. For example, more than 90% of all volcanic rock on Earth is basalt. The term basalt is applied to most low viscosity dark silicate lavas, regardless of composition. Basalt is a mafic, extrusive and fine grained igneous rock Click on Term to Read More, High-Mg Suite (HMS), High-Alkali Suite (HAS), ferroan anorthositeA phaneritic, intrusive igneous rock made with a modal composition (i.e. volume%) > 90% plagioclase feldspar of undefined composition (anorthitic to albitic, or combination thereof), and a small mafic component between 0 - 10% such as pyroxene, ilmenite, magnetite, and olivine 1. The name anorthosite is derived from the calcium-rich Click on Term to Read More (FAN), and impact-melt lithologies dispersed in the matrixFine grained primary and silicate-rich material in chondrites that surrounds chondrules, refractory inclusions (like CAIs), breccia clasts and other constituents. Click on Term to Read More. The KREEP-bearing assemblages are composed of granophyric textured clasts consisting of intergrowths of silicaSilicon dioxide, SiO2. and K-feldspar, together with the high-temperature mineralInorganic substance that is (1) naturally occurring (but does not have a biologic or man-made origin) and formed by physical (not biological) forces with a (2) defined chemical composition of limited variation, has a (3) distinctive set of of physical properties including being a solid, and has a (4) homogeneous Click on Term to Read More zirconium oxide, or baddeleyiteA rare zirconium oxide (ZrO2) mineral, often formed as a shock-induced breakdown product of zircon. This mineral can be found in some lunar and martian meteorites. Click on Term to Read More, and the Fe(Zr,Y)Ti-silicate known as tranquillityite, a mineral first recognized as a late-stage fractional crystallizationA crystallization process in which minerals crystallizing from a magma are isolated from contact with the liquid. It is a key process in the formation of igneous rocks during the process of magmatic differentiation. Also known as crystal fractionation. Click on Term to Read More product in Apollo 11 and 12 basalts. Other mineral fragments identified in NWA 4485 include olivineGroup of silicate minerals, (Mg,Fe)2SiO4, with the compositional endpoints of forsterite (Mg2SiO4) and fayalite (Fe2SiO4). Olivine is commonly found in all chondrites within both the matrix and chondrules, achondrites including most primitive achondrites and some evolved achondrites, in pallasites as large yellow-green crystals (brown when terrestrialized), in the silicate portion Click on Term to Read More, pyroxeneA class of silicate (SiO3) minerals that form a solid solution between iron and magnesium and can contain up to 50% calcium. Pyroxenes are important rock forming minerals and critical to understanding igneous processes. For more detailed information, please read the Pyroxene Group article found in the Meteoritics & Classification Click on Term to Read More, plagioclaseAlso referred to as the plagioclase feldspar series. Plagioclase is a common rock-forming series of feldspar minerals containing a continuous solid solution of calcium and sodium: (Na1-x,Cax)(Alx+1,Si1-x)Si2O8 where x = 0 to 1. The Ca-rich end-member is called anorthite (pure anorthite has formula: CaAl2Si2O8) and the Na-rich end-member is albite Click on Term to Read More, ilmeniteTi-Fe oxide, TiFeO3, found in achondrites, lunar mare basalts, and shergottites. Ilmenite forms as a primary mineral in mafic igneous rocks. It crystallizes relatively early out of a magma before most of the other minerals, and as a result, the heavier crystals of ilmenite precipitate to the bottom of the magma Click on Term to Read More, chromiteBrownish-black oxide of chromium and iron (Cr-Fe oxide), Cr2FeO4, found in many meteorite groups. Click on Term to Read More, K-feldspar, apatite, merrillite, silica, Fe-metal, and FeS, most reflecting derivation from a KREEP-rich precursor magmaMolten silicate (rock) beneath the surface of a planetary body or moon. When it reaches the surface, magma is called lava. Click on Term to Read More (Arai et al., 2009) referred to as urKREEP. The investigators observed that some of these KREEPLunar igneous rock rich in potassium (K), rare-earth elements (REE), phosphorus (P), thorium, and other incompatible elements. These elements are not incorporated into common rock-forming minerals during magma crystallization, and become enriched in the residual magma and the rocks that ultimately crystallize from it. Click on Term to Read More basalt clasts exhibit chemical zoning and thick exsolutionSegregation, during cooling, of a homogeneous solid solution into two or more different solids. Click on Term to Read More lamellae, attesting to slower cooling conditions at a deeper location compared to the Apollo mare basalts. The matrix also contains a variety of glasses, some containing vesicles and others taking the form of spherules enriched in P and K. In their study of apatite grains in NWA 4472, the pairing to NWA 4485, Tartèse et al. (2014) found that they contain moderate amounts of water, in the range of 2,000–6,000 ppmParts per million (106). Click on Term to Read More. Associated isotopic studies on the apatite demonstrated elevated δ37Cl values compared to terrestrial values, which suggests this meteorite has retained its original lunar isotopic signature. Moreover, they recognized that the δD values are consistent with lunar rocks associated with HMS, HAS, and KREEP-rich basalts.
The bulk composition of NWA 4485 reflects a high REEOften abbreviated as “REE”, these 16 elements include (preceded by their atomic numbers): 21 scandium (Sc), 39 Yttrium (Y) and the 14 elements that comprise the lanthanides excluding 61 Promethium, an extremely rare and radioactive element. These elements show closely related geochemical behaviors associated with their filled 4f atomic orbital. Click on Term to Read More abundance with a strong negative Eu anomaly, with overall incompatible elementSubstance composed of atoms, each of which has the same atomic number (Z) and chemical properties. The chemical properties of an element are determined by the arrangement of the electrons in the various shells (specified by their quantum number) that surround the nucleus. In a neutral atom, the number of Click on Term to Read More abundances in the range of the only known KREEP-rich lunaites—the impact-melt breccias Sayh al Uhaymir 169 and Dhofar 1442. SaU 169 contains ~4.0 b.y. old clasts containing very high-K KREEP which best reflect the composition of primordial urKREEP (Lin et al. 2010). Basaltic clasts in NWA 4472/4485 sample low-Ti to very low-Ti source regions and exhibit a range of metamorphicRocks that have recrystallized in a solid state due to changes in temperature, pressure, and chemical environment. Click on Term to Read More textures. Some of these are fayalite-rich, quenched-textured glass thought to be derived from impact melting of mare basalt lithologies. Also present are a variety of feldspathic impact-melt, fragmental, and granulitic breccias, as well as metalElement that readily forms cations and has metallic bonds; sometimes said to be similar to a cation in a cloud of electrons. The metals are one of the three groups of elements as distinguished by their ionization and bonding properties, along with the metalloids and nonmetals. A diagonal line drawn Click on Term to Read More clasts and glass spherules, all consistent with lithification within the lunar regolith.
The composition of NWA 4472/4485 is similar to that of the Th-rich, mafic, LKFM (low-K Fra Mauro) impact-melt breccias recognized from the Apollo collection; specifically, group-C melt breccias of Apollo 15, group-1S melt breccias of Apollo 16, and the aphanitic and poikilitic impact-melt breccias of Apollo 17 (Korotev 2000). The four constituents of the LKFM material—KREEP noriteIgneous rock composed of 90% plagioclase, 95% orthopyroxene (low-Ca pyroxene) and less than 10% olivine. Norite is most commonly found in the lunar (highlands) meteorites but has also been found in about a dozen diogenites, a few shergottites, and a very small number of other achondrite types. Gabbro is very Click on Term to Read More, forsteritic dunite, feldspathic upper crustOutermost layer of a differentiated planet, asteroid or moon, usually consisting of silicate rock and extending no more than 10s of km from the surface. The term is also applied to icy bodies, in which case it is composed of ices, frozen gases, and accumulated meteoritic material. On Earth, the Click on Term to Read More, and FeNi-metal—are thought to be the likely products of a basin-sized impact into the ancient ‘Great Lunar Hot Spot’, which created the Imbrium basin within the Th-rich Procellarum KREEP Terrane (PKT) (Korotev, 1999). The impactor is thought to have been an iron meteoriteMeteorite composed mainly of iron (Fe) and nickel (Ni) in the form of two alloys, kamacite and taenite. Due to their metallic makeup and extraordinary weight, iron meteorites are easily distinguished from ordinary rocks. Also, because they rarely break up in the air and suffer much less from the effects Click on Term to Read More that mixed upper mantleMain silicate-rich zone within a planet between the crust and metallic core. The mantle accounts for 82% of Earth's volume and is composed of silicate minerals rich in Mg. The temperature of the mantle can be as high as 3,700 °C. Heat generated in the core causes convection currents in Click on Term to Read More dunite with KREEP-contaminated Mg-rich magma, and incorporated clasts of ferroan anorthositic upper crust. The LKFM composition is unique to the PKT, and with its high FeO (noritic) composition and incompatible element abundances (>10 ppm Sm; 5.9–7.9 ppm Th), NWA 4472/4485 is likely derived from this nearside region (Joy et al., 2008). Other possible source locations are northwest of Sinus Iridium within the Jura mountains, northwest of Sinus Roris at Herschel craterBowl-like depression ("crater" means "cup" in Latin) on the surface of a planet, moon, or asteroid. Craters range in size from a few centimeters to over 1,000 km across, and are mostly caused by impact or by volcanic activity, though some are due to cryovolcanism. Click on Term to Read More, regions of the MonsLarge area of high relief; mountain (pl. montes). Click on Term to Read More Alpes formation in western Mare Imbrium, regions of the Apennine mountains near Mons Caucasus and Mons Bradley near Apollo 15, and regions near the craters Ptolemaeus and Lalande, the latter suggested to be the source location of SaU 169.
Calzada-Diaz et al. (2015) compared compositional and age data from a large number of lunar meteoritesAchondrite meteorites from the surface of the Moon. Most were found in the hot deserts of northern Africa and Oman and others were found in the cold desert of Antarctica, although one, a 19-gram specimen, was recovered in 1990 from Calcalong Creek, Australia. These stones are of great importance because, Click on Term to Read More with elemental remote sensing data obtained by the Lunar Prospector gamma rayMost energetic form of radiation, similar to x-rays and light, except with shorter wavelengths (<0.01 nm) and higher energies (>105 eV). Despite their high energies and penetrating power, g-rays from cosmic sources are absorbed by the atmosphere. In nuclear reactions, decay by g-ray emission permits an excited nucleus drop lower Click on Term to Read More spectrometer, primarily for Fe, Ti, and Th, to better constrain the meteorite’s source regions. For the KREEP-rich basaltic melt breccia NWA 4485/4472, plausible ejection sites were identified near the John Herschel crater and in Mons Caucasus, having a composition consistent with ejectaFractured and/or molten rocky debris thrown out of a crater during a meteorite impact event, or, alternatively, material, including ash, lapilli, and bombs, erupted from a volcano. Click on Term to Read More from the Imbrium basin (see image below). Image credit: A. Calzada-Diaz et al. MAPS, vol. 50, #2, p. 220 (2015) ‘Constraining the source regions of lunar meteorites using orbital geochemical data’ (http://dx.doi.org/10.1111/maps.12412) Establishment of a thorough chronological history of this lunar rock following the initial basin-forming impact, and including the time spent on the lunar surface, in Moon–Earth transitWhen a small celestial body moves in front of a much larger one (as when Mercury or Venus appears in silhouette against the solar disk or when a satellite passes in front of Jupiter or Saturn). The shadow of a satellite may also transit the disk of its primary., and in terrestrial residence has begun (Joy et al., 2009). Cosmogenic Ar–Ar data are indicative of a ~300 m.y. near-surface residence as part of the ancient lunar regolith. The Pb–Pb and U–Pb ages were calculated from the phosphates fluorapatite and merrillite in matrix and basalt clasts, as well as from zirconOrthosilicate mineral, Zr(SiO4), observed in all terrestrial rocks type and in ordinary chondrites, eucrites, mesosiderites, and lunar rocks. grains in the KREEP basalt component (Joy et al., 2011). The ages found within this regolith breccia reflect a diversity of lithic fragments with a wide range of crystallizationPhysical or chemical process or action that results in the formation of regularly-shaped, -sized, and -patterned solid forms known as crystals. Click on Term to Read More ages (~4.35–3.94 b.y.); the younger ages in this range are consistent with those of Apollo KREEPy mare basalts possibly dating the formation of Mare Imbrium, while the oldest ages were derived from a matrix apatite grain and might reflect the crystallization of the HAS lithology. The lower Ar–Ar apparent age of 1.7–2.2 b.y. obtained for trapped solar windSupersonic flow of high-speed charged particles continuously blowing off a star (mostly e- and p+). When originating from stars other than the Sun, it is sometimes called a "stellar" wind. The solar wind may be viewed as an extension of the corona into interplanetary space. The solar wind emanates radially Ar is thought to reflect a recent impact-resetting event which could represent the consolidation of the NWA 4472/4485 meteorite components.
A more thorough treatment of the chemical classification of lunar meteorites can be found on the WUSL—Lunar Meteorites website, including information on the other (unpaired) KREEP-rich meteorites SaU 169 and Dhofar 961/960/925/SaU 449, the KREEPy clastA mineral or rock fragment embedded in another rock. Click on Term to Read More bearing meteorites Calcalong Creek and Y-983885, and the KREEP basalt meteorites comprising the NWA 733 pairing group, the LAP pairing group, and Dhofar 287a.
NWA 4472/4485 contains Sr and Ba indicative of terrestrial weathering. Both portions of the meteorite also contain high Br concentrations, suggesting that they were contaminated by seawater. The photo of NWA 4485 shown above is a 0.32 g partial slice, while that pictured below is the uncut mass as found (both photos courtesy of Chladni’s-Heirs.com).
Photo courtesy of Chladni’s-Heirs.com
Lunar Feldspathic BrecciaWork in Progress ... A rock that is a mechanical mixture of different minerals and/or rock fragments (clasts). A breccia may also be distinguished by the origin of its clasts: (monomict breccia: monogenetic or monolithologic, and polymict breccia: polygenetic or polylithologic). The proportions of these fragments within the unbrecciated material Click on Term to Read More (crystalline impact-melt) Purchased January 9, 2001 no coordinates recorded An oriented lunar meteoriteWork in progress. A solid natural object reaching a planet’s surface from interplanetary space. Solid portion of a meteoroid that survives its fall to Earth, or some other body. Meteorites are classified as stony meteorites, iron meteorites, and stony-iron meteorites. These groups are further divided according to their mineralogy and Click on Term to Read More weighing 1,015 g was originally found by a Berber nomad in late 2000 during a desert search, probably in Algeria. It was later sold in Morocco to a group of American meteorite collectors. Although much of the fusion crustMelted exterior of a meteorite that forms when it passes through Earth’s atmosphere. Friction with the air will raise a meteorite’s surface temperature upwards of 4800 K (8180 °F) and will melt (ablate) the surface minerals and flow backwards over the surface as shown in the Lafayette meteorite photograph below. Click on Term to Read More on this meteorite has been replaced by desert varnish, the interior shows little sign of terrestrial weathering. Northwest Africa 482 is a polymict, crystalline impact-melt breccia, consisting of scattered white clasts of anorthositeA phaneritic, intrusive igneous rock made with a modal composition (i.e. volume%) > 90% plagioclase feldspar of undefined composition (anorthitic to albitic, or combination thereof), and a small mafic component between 0 - 10% such as pyroxene, ilmenite, magnetite, and olivine 1. The name anorthosite is derived from the calcium-rich Click on Term to Read More within a fine-grained matrixFine grained primary and silicate-rich material in chondrites that surrounds chondrules, refractory inclusions (like CAIs), breccia clasts and other constituents. Click on Term to Read More of anorthitic plagioclaseAlso referred to as the plagioclase feldspar series. Plagioclase is a common rock-forming series of feldspar minerals containing a continuous solid solution of calcium and sodium: (Na1-x,Cax)(Alx+1,Si1-x)Si2O8 where x = 0 to 1. The Ca-rich end-member is called anorthite (pure anorthite has formula: CaAl2Si2O8) and the Na-rich end-member is albite Click on Term to Read More (An96.3), olivineGroup of silicate minerals, (Mg,Fe)2SiO4, with the compositional endpoints of forsterite (Mg2SiO4) and fayalite (Fe2SiO4). Olivine is commonly found in all chondrites within both the matrix and chondrules, achondrites including most primitive achondrites and some evolved achondrites, in pallasites as large yellow-green crystals (brown when terrestrialized), in the silicate portion Click on Term to Read More, pigeoniteLow-Ca clinopyroxene, (Ca,Mg,Fe)SiO3, found as a major mineral in eucrites and shergottites. In order to be considered pigeonite, the clinopyroxene must contain 5 to 20 mol % of calcium (Wo5 - 20). Chondrites of petrologic types 4 and below contain significant low-Ca clinopyroxene. During metamorphism to higher temperatures, all existing, and augiteHigh-Ca clinopyroxene, (Ca,Mg,Fe)SiO3, that occurs in many igneous rocks, particularly those of basaltic composition. In order to be considered augite, the clinopyroxene must contain 20 to 45 mol % of calcium (Wo20 - 45). An important and unique Martian meteorite is NWA 8159, that has been classified as an augite Click on Term to Read More, with rare troiliteBrass colored non-magnetic Fe sulfide, FeS, found in a variety of meteorites., FeNi-metal (Ni-rich), ilmeniteTi-Fe oxide, TiFeO3, found in achondrites, lunar mare basalts, and shergottites. Ilmenite forms as a primary mineral in mafic igneous rocks. It crystallizes relatively early out of a magma before most of the other minerals, and as a result, the heavier crystals of ilmenite precipitate to the bottom of the magma Click on Term to Read More, and whitlockite. Besides anorthosite clasts, other clastA mineral or rock fragment embedded in another rock. Click on Term to Read More types that are present include troctoliteTroctolite is an intrusive igneous rock consisting of plagioclase feldspar and olivine. It is a member of gabbroic rocks family. It is compositionally similar to gabbro. The main difference is that it does not contain pyroxene or contains very little while it is a major mineral in gabbro. It can Click on Term to Read More, anorthositic troctolite, troctoliticTroctolite is an intrusive igneous rock consisting of plagioclase feldspar and olivine. It is a member of gabbroic rocks family. It is compositionally similar to gabbro. The main difference is that it does not contain pyroxene or contains very little while it is a major mineral in gabbro. It can Click on Term to Read More anorthosite, and pleonaste spinelMg-Al oxide, MgAl2O4, found in CAIs.. No KREEPLunar igneous rock rich in potassium (K), rare-earth elements (REE), phosphorus (P), thorium, and other incompatible elements. These elements are not incorporated into common rock-forming minerals during magma crystallization, and become enriched in the residual magma and the rocks that ultimately crystallize from it. Click on Term to Read More, regolithMixture of unconsolidated rocky fragments, soil, dust and other fine granular particles blanketing the surface of a body lacking an atmosphere. Regolith is the product of "gardening" by repeated meteorite impacts, and thermal processes (such as repeated heating and cooling cycles). Click on Term to Read More, Mg-suite, or mareBroad low plains surrounded by basin-forming mountains, originally thought to be a sea (pl. maria). This term is applied to the basalt-filled impact basins common on the face of the Moon visible from Earth. Click on Term to Read More components have been observed (Daubar et al., 2002), and thus a lunar far side origin is considered more favorable.
The rock was melted and brecciated, and clasts were introduced during a severe shock event, possibly occurring ~3.75 b.y. ago. Isotopic composition and elemental abundance studies indicate that the impactor component in the NWA482 impact melt breccia had a bulk composition comparable to an EH chondriteChondrites are the most common meteorites accounting for ~84% of falls. Chondrites are comprised mostly of Fe- and Mg-bearing silicate minerals (found in both chondrules and fine grained matrix), reduced Fe/Ni metal (found in various states like large blebs, small grains and/or even chondrule rims), and various refractory inclusions (such Click on Term to Read More (Puchtel et al., 2008). Thereafter, the rock experienced a moderate shock event, possibly occurring ~2.4 b.y. ago, which resulted in shock meltingComplete melting of target material produced by the shock of a meteoric impact. Different minerals will experience certain shock effects at different pressures and temperatures. For example, dense target rocks like anorthosite will typically experience whole rock melting above 50 to 60 GPa, while chondritic rocks require more than 70 Click on Term to Read More and the formation of the black, vesiculated, shock-melt veins and melt pockets in the form of quenched glass. Ultimately, this rock was ejected from the Moon in a separate impact event, likely responsible for some of the shock veins. This lunaite has a relatively high porosityThe volume percentage of a rock that consists of void space. Vesicular porosity is a type of porosity resulting from the presence of vesicles, or gas bubbles, in igneous rock such as the pumice presented here. Vesicular porosity is very rare in meteorites and is often associated with slag, one Click on Term to Read More of ~13% (Warren et al., 2005). A more comprehensive treatment of this special meteorite is maintained by the owners at LunarRock.com.
Northwest Africa 482 is similar to sample #65015 that was returned by Apollo 16 from the lunar highlandsThe highly cratered, topographically high, ancient crust of the Moon. This region is composed mostly of anorthosite, a plagioclase-rich rock. Click on Term to Read More, which is thought to be a sample of ancient lunar highlands, probably 4.4–4.5 b.y. old. However, in contrast to the Apollo samples, NWA 482 is derived from a KREEP-deficient terrane, more consistent with a location on the far side of the Moon. However, since an impact-melt breccia could be formed at a significant depth beneath the large-ion-lithophile contaminated regolith, its low-Th, low-Fe signature by itself is not an adequate determinant for either a nearside or a farside origin for this type of lunar meteorite (R. Korotev).
Calzada-Diaz et al. (2015) compared compositional and age data from a large number of lunar meteoritesAchondrite meteorites from the surface of the Moon. Most were found in the hot deserts of northern Africa and Oman and others were found in the cold desert of Antarctica, although one, a 19-gram specimen, was recovered in 1990 from Calcalong Creek, Australia. These stones are of great importance because, Click on Term to Read More with elemental remote sensing data obtained by the Lunar Prospector gamma rayMost energetic form of radiation, similar to x-rays and light, except with shorter wavelengths (<0.01 nm) and higher energies (>105 eV). Despite their high energies and penetrating power, g-rays from cosmic sources are absorbed by the atmosphere. In nuclear reactions, decay by g-ray emission permits an excited nucleus drop lower Click on Term to Read More spectrometer, primarily for Fe, Ti, and Th, to better constrain the meteorite’s source regions. For the crystalline impact-melt breccia NWA 482, plausible ejection sites were identified in the Feldspathic Highland Terrane on the farside (see image below). Image credit: A. Calzada-Diaz et al. MeteoriticsScience involved in the study of meteorites and related materials. Meteoritics are closely connected to cosmochemistry, mineralogy and geochemistry. A scientist that specializes in meteoritics is called a meteoriticist. Click on Term to Read More & Planetary Science, vol. 50, p. 222 (2015) Noble gasElement occurring in the right-most column of the periodic table; also called "inert" gases. In these gases, the outer electron shell is completely filled, making them very unreactive. Click on Term to Read More studies indicate that NWA 482 records the longest residence in the lunar regolith observed to date—2.07 (±0.42) b.y—which occurred at a depth of >2.8 m (>500 g/cm² [shielding depth] divided by 1.8 g/cm³ [ave. regolith density]) (Lorenzetti et al., 2005). Northwest Africa 482 has a cosmic-ray exposure ageTime interval that a meteoroid was an independent body in space. In other words, the time between when a meteoroid was broken off its parent body and its arrival on Earth as a meteorite - also known simply as the "exposure age." It can be estimated from the observed effects Click on Term to Read More of 280 t.y., and it arrived on Earth 8.6 (±1.3) t.y. ago (Nishiizumi, 2003). According to Nishiizumi and Caffee (2010), this relatively long Moon–Earth transitWhen a small celestial body moves in front of a much larger one (as when Mercury or Venus appears in silhouette against the solar disk or when a satellite passes in front of Jupiter or Saturn). The shadow of a satellite may also transit the disk of its primary. time would be consistent with a launch from a depth of >5.6 m. They determined that shallower launches from depths of <1–4.7 m correspond to the shortest transit times of <0.1 m.y. Through studies of cosmogenic nuclides, its pre-atmospheric diameter was calculated to be ~11–14 cm, while the presence of 26Al is indicative of relatively low ablationGradual removal of the successive surface layers of a material through various processes. • The gradual removal and loss of meteoritic material by heating and vaporization as the meteoroid experiences frictional melting during its passage through the atmosphere. The resulting plasma ablates the meteor and, in cases where a meteor Click on Term to Read More, removing 1–1.5 cm from its surface.
The specimen of NWA 482 pictured above is a 0.29 g partial slice displaying intricate microbrecciation. The top photo below shows the slice from which the above specimen was removed, while the bottom photo below shows a close-up of the large shock vein within the slice.
Photos courtesy of Anne Black—Impactika Meteorites The photos below show the complete oriented main massLargest fragment of a meteorite, typically at the time of recovery. Meteorites are commonly cut, sliced or sometimes broken thus reducing the size of the main mass and the resulting largest specimen is called the "largest known mass". Click on Term to Read More exhibiting flow lines in the thin remnant crustOutermost layer of a differentiated planet, asteroid or moon, usually consisting of silicate rock and extending no more than 10s of km from the surface. The term is also applied to icy bodies, in which case it is composed of ices, frozen gases, and accumulated meteoritic material. On Earth, the Click on Term to Read More or weathering rind. On the right is what might be the most beautiful photo taken of this awesome lunaite, showing a large cut face. A sizable portion of this rare meteorite has been donated for scientific study.
Photos courtesy of Jim Strope—darksideofthemoon.com
Lunar Feldspathic BrecciaWork in Progress ... A rock that is a mechanical mixture of different minerals and/or rock fragments (clasts). A breccia may also be distinguished by the origin of its clasts: (monomict breccia: monogenetic or monolithologic, and polymict breccia: polygenetic or polylithologic). The proportions of these fragments within the unbrecciated material Click on Term to Read More (impact-melt) Found January 2003 19° 19.9′ N., 54° 47.0′ E. Nine individual stones, having a total combined weight of 245.46 g and exhibiting heterogeneous compositions, were recovered by a German expedition searching in Wadi Quitbit within the Dhofar dense collection area of Oman. The expedition was searching within the strewnfield in which the lunar pairing group of Dhofar 303, 305, 306, 307, 309, 310, 311, 730, 731, 489 (found 24 km away), 908, 909, 911 (comprising nine separate stones), 950, and 1085 was recovered. Terrestrial weathering has produced significant staining from hematiteFe-oxide mineral (Fe2O3) that may be the major cause of the red color on Mars. Coarser-grained gray hematite has the same chemical formula as the red variety, but a different crystalline structure. Deposits of gray hematite found in the Terra Meridiani region of Mars may suggest that water once circulated Click on Term to Read More (R. Korotev).
The finder of the individual Dhofar 908 stone, Norbert Classen, adopted the term ‘Rosetta Stone’ to describe this 81 g lunaite due to its having three distinct lithologies that link the diverse finds Dhofar 302, 303, 305, 306, 307, 309, 310, 311, 730, 731, and 489 together; most of these other stones represent only one of the three lithologies. Importantly, Dhofar 908 established a clear pairing relationship among all of these separate finds (see photo below).
Following the analysis at the Institut für Planteologie in Münster, these meteorites were classified as lunar feldspathic breccias, specifically, impact-melt breccias. Interestingly, the lunar feldspathic fragmental breccia that comprises the individual stones Dhofar 081, 280, 910, and 1224, was found in the western half of this same strewnfield, which encompasses an area of 1.4 × 1.2 km—an astounding case of overlapping lunar strewnfields.
Cosmogenic nuclideA nuclear species characterized by Z protons and N neutrons. Click on Term to Read More studies of Dhofar 908 based on 10Be and 26Al have enabled the determination of the excavation depth on the Moon (>6 m), the Moon–Earth transitWhen a small celestial body moves in front of a much larger one (as when Mercury or Venus appears in silhouette against the solar disk or when a satellite passes in front of Jupiter or Saturn). The shadow of a satellite may also transit the disk of its primary. time (4 ±1 t.y.), and the terrestrial age (~300 t.y.) (Nishiizumi and Caffee, 2006). Sm–Nd data yield a crystallizationPhysical or chemical process or action that results in the formation of regularly-shaped, -sized, and -patterned solid forms known as crystals. Click on Term to Read More age of 4.31 (±0.07) b.y., and might reflect derivation from magnesian troctolitic-anorthosite precursor material from plutons that intruded into the early ferroan crustOutermost layer of a differentiated planet, asteroid or moon, usually consisting of silicate rock and extending no more than 10s of km from the surface. The term is also applied to icy bodies, in which case it is composed of ices, frozen gases, and accumulated meteoritic material. On Earth, the Click on Term to Read More after solidification of the lunar magma oceanCompletely molten surfaces of terrestrial planets or moons that formed soon after accretion. Samples returned by the Apollo missions provide evidence of a lunar magma ocean, crystallization of which produced a stratified Moon with a low-density crust formed by accumulation of the mineral plagioclase overlying a higher density mantle of Click on Term to Read More (Nyquist et al., 2010). Gross et al. (2012) have presented evidence found in most feldspathic highlands meteorites that a global lunar magmaMolten silicate (rock) beneath the surface of a planetary body or moon. When it reaches the surface, magma is called lava. Click on Term to Read More ocean did not form, and they lack features of such a scenario; i.e., they contain no ferroan anorthosites, KREEPLunar igneous rock rich in potassium (K), rare-earth elements (REE), phosphorus (P), thorium, and other incompatible elements. These elements are not incorporated into common rock-forming minerals during magma crystallization, and become enriched in the residual magma and the rocks that ultimately crystallize from it. Click on Term to Read More, or Mg-suite rocks. Instead, anorthositeA phaneritic, intrusive igneous rock made with a modal composition (i.e. volume%) > 90% plagioclase feldspar of undefined composition (anorthitic to albitic, or combination thereof), and a small mafic component between 0 - 10% such as pyroxene, ilmenite, magnetite, and olivine 1. The name anorthosite is derived from the calcium-rich Click on Term to Read More intrusions rise continuously in diapirs, resulting in compositional diversity among the crustal regions.
An Ar–Ar age for the mostly troctoliticTroctolite is an intrusive igneous rock consisting of plagioclase feldspar and olivine. It is a member of gabbroic rocks family. It is compositionally similar to gabbro. The main difference is that it does not contain pyroxene or contains very little while it is a major mineral in gabbro. It can Click on Term to Read MorematrixFine grained primary and silicate-rich material in chondrites that surrounds chondrules, refractory inclusions (like CAIs), breccia clasts and other constituents. Click on Term to Read More material of Dhofar 908 was found to be 4,256 (±20) m.y., taking into consideration evidence for solar windSupersonic flow of high-speed charged particles continuously blowing off a star (mostly e- and p+). When originating from stars other than the Sun, it is sometimes called a "stellar" wind. The solar wind may be viewed as an extension of the corona into interplanetary space. The solar wind emanates radially Ar trapped during residence on the lunar surface. This age may reflect material derived from an old basin within early-formed anorthositic crust on the lunar farside in which low Th and FeO exist (Karouji et al., 2010). The crustal asymmetries that exist between the farside and nearside can be explained by the tilted convectionTransfer of heat energy by moving material. Temperatures increases with depth in planetary objects. Deep hot less-dense material physically rises and cools, releasing heat and becoming denser. The now cooler denser material sinks back into deeper regions, where it will be reheated and rise again. Convection is an important mechanism Click on Term to Read More model. A potential ejection site for the Dhofar pairing group is considered to be the Derichlet-Jackson basin.
Studies of Dhofar 489, a member of the pairing group, revealed the presence of unique magnesian anorthosite clasts and a spinelMg-Al oxide, MgAl2O4, found in CAIs.troctoliteTroctolite is an intrusive igneous rock consisting of plagioclase feldspar and olivine. It is a member of gabbroic rocks family. It is compositionally similar to gabbro. The main difference is that it does not contain pyroxene or contains very little while it is a major mineral in gabbro. It can Click on Term to Read MoreclastA mineral or rock fragment embedded in another rock. Click on Term to Read More. Its bulk analysis is highly depleted in Th (proxy for ITEs) and FeO (Takeda et al., 2007). In addition, studies of the paired stone Dhofar 309 revealed clasts of anorthosite and troctolite composition, considered to be metamorphosed and annealed crystalline rocks associated with an impact-melt pool. A reddish-orange clast found in these samples has a crystalline texture and contains plagioclaseAlso referred to as the plagioclase feldspar series. Plagioclase is a common rock-forming series of feldspar minerals containing a continuous solid solution of calcium and sodium: (Na1-x,Cax)(Alx+1,Si1-x)Si2O8 where x = 0 to 1. The Ca-rich end-member is called anorthite (pure anorthite has formula: CaAl2Si2O8) and the Na-rich end-member is albite Click on Term to Read More crystals and rounded olivineGroup of silicate minerals, (Mg,Fe)2SiO4, with the compositional endpoints of forsterite (Mg2SiO4) and fayalite (Fe2SiO4). Olivine is commonly found in all chondrites within both the matrix and chondrules, achondrites including most primitive achondrites and some evolved achondrites, in pallasites as large yellow-green crystals (brown when terrestrialized), in the silicate portion Click on Term to Read More grains; it is thought to be an impact-melt clast derived from spinel troctolite, but which includes a pyroxeneA class of silicate (SiO3) minerals that form a solid solution between iron and magnesium and can contain up to 50% calcium. Pyroxenes are important rock forming minerals and critical to understanding igneous processes. For more detailed information, please read the Pyroxene Group article found in the Meteoritics & Classification Click on Term to Read More component derived from noriteIgneous rock composed of 90% plagioclase, 95% orthopyroxene (low-Ca pyroxene) and less than 10% olivine. Norite is most commonly found in the lunar (highlands) meteorites but has also been found in about a dozen diogenites, a few shergottites, and a very small number of other achondrite types. Gabbro is very Click on Term to Read More.
Studies of the paired Dhofar 307 led to the discovery of magnesian anorthositic granulite clasts, originally derived from impact melts, some of which contain large olivine fragments embedded in a glassy plagioclase matrix (Takeda et al., 2008, 2010). These olivine fragments may represent ejected mantleMain silicate-rich zone within a planet between the crust and metallic core. The mantle accounts for 82% of Earth's volume and is composed of silicate minerals rich in Mg. The temperature of the mantle can be as high as 3,700 °C. Heat generated in the core causes convection currents in Click on Term to Read More rock from the massive impact that created the largest impact craterCrater formed by high-speed impact of a meteoroid, asteroid, or comet on a solid surface. Craters are a common feature on most moons (an exception is Io), asteroids, and rocky planets, and range in size from a few cm to over 1,000 km across. There is a general morphological progression Click on Term to Read More in the Solar SystemThe Sun and set of objects orbiting around it including planets and their moons and rings, asteroids, comets, and meteoroids., the South Pole–Aitken basin, located on the lunar farside. These magnesian anorthositic granulite clasts may be ancient (up to 4.3 b.y.), and are thought to represent basaltic plutons which were emplaced into plagioclase-rich crust following solidification of the lunar magma ocean. The bulk compositions of the anorthositic granulite clasts (FeO ~4.5 wt%; Al2O3 ~28 wt%; Th <1 ppmParts per million (106). Click on Term to Read More) are similar to those calculated for the Feldspathic Highlands Terrane (FHT) on the lunar farside. The magnesian anorthosite clasts represent a distinct geochemical lunar component that is widespread across the lunar surface (Treiman et al., 2010). These clasts contain too much magnesium to be related to the Ferroan Anorthosite Suite (FAN) components, and are too feldspathic and lacking in KREEP to be related to the Mg-Suite components, both of which are typical contaminates in lunar breccias recovered from the nearside of the Moon.
Since Dhofar 908 and its pairing group represent a quickly cooled impact-melt breccia that could have formed at a significant depth beneath a regolithMixture of unconsolidated rocky fragments, soil, dust and other fine granular particles blanketing the surface of a body lacking an atmosphere. Regolith is the product of "gardening" by repeated meteorite impacts, and thermal processes (such as repeated heating and cooling cycles). Click on Term to Read More, which could potentially have been contaminated with incompatible elements, its low-Th, low-FeO signature taken by itself is not an adequate determinant for either a nearside or a farside origin for this type of lunar meteoriteWork in progress. A solid natural object reaching a planet’s surface from interplanetary space. Solid portion of a meteoroid that survives its fall to Earth, or some other body. Meteorites are classified as stony meteorites, iron meteorites, and stony-iron meteorites. These groups are further divided according to their mineralogy and Click on Term to Read More (R. Korotev). However, when these analyses are considered together, along with the possible discovery of a norite component, it can be inferred that the origin of this pairing group is most likely the lunar farside—possibly from the area of the South Pole–Aitken basin, or perhaps the FHT at the northern portion of the lunar farside.
An alternative formation scenario has been proposed by Takeda et al. (2008, 2010) in which a large impact into magnesian anorthosites, likely on the northern farside, excavated a basin at least 80 km in diameter and produced an extensive melt sheet. Deep-seated lithologies present in the meteorite were excavated as well. Rapid cooling and subsequent impact gardening within this basin led to the final consolidation of this brecciated rock. A large basin containing many craters in which the Dhofar 908 breccia may have formed is the Dirichlet-Jackson basin, located in the low-Th region of the farside. The mineralogy, chemistry, and petrologyScience dealing with the origin, history, occurrence, chemical composition, structure and classification of rocks. Click on Term to Read More of the various members of this pairing group indicate that they were all derived from a common precursor lithology, one having a spinel troctolite composition consistent with a location at a significant depth (>5 m) within the crust.
The specimen pictured above is a 0.143 g very thin partial slice from the main massLargest fragment of a meteorite, typically at the time of recovery. Meteorites are commonly cut, sliced or sometimes broken thus reducing the size of the main mass and the resulting largest specimen is called the "largest known mass". Click on Term to Read More of Dhofar 908. The photo below shows the main mass of Dhofar 908, the first stone to be found, weighing 81.43 g. Dhofar 908 was exported by permit from the Ministry of Commerce and Industry, Sultanate of Oman. The bottom photo is a beautiful 0.61 g thin slice from the Dhofar 908 main mass showing three separate lithologies (3.1 cm in longest dimension). <!–Click to see a high resolution photo of a 2.54 g complete slice of this meteorite, courtesy of the finder, Norbert Classen. –> Photo courtesy of Norbert Classen click on photo for a magnified view
Three Lithologies: left: IMB clast-poor lithology top: mature regolith w/ dark matrix bottom: IMB clast-rich lithology Photo courtesy of Stephan Kambach
For additional information on the magnesium-rich granulites, read the PSRD article by Linda Martel—‘Unraveling the Origin of the Lunar Highlands Crust’, Sept. 2010.
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